Canon EOS 5D Mark III Standard Zoom Lens Kit Owner's Manual

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You can shoot two to nine exposures to be merged into one image.
 If you 
shoot multiple-exposure images with Live View shooting (p.197), you 
can see how the single exposures merge while shooting.
1
Press the <b> button.
2
Select multiple exposure.
 
Turn the <5> dial to select [P], 
then press <
0>.
X
The multiple exposure setting screen 
will appear.
3
Set [Multiple exposure].
 
Select [On:Func/Ctrl] or 
[On:ContShtng], then press <
0>.
 
To quit shooting multiple exposures, 
select [Disable].
 
On: Func/Ctrl (Function and control priority)
Convenient when you want to shoot multiple exposures while 
checking the result as you proceed. During continuous shooting, the 
continuous shooting speed will decrease greatly.
 
On: ContShtng (Continuous shooting priority)
Geared for continuous multiple-exposure shooting of a moving 
subject. Continuous shooting is possible, but the following 
operations are disabled during shooting: menu viewing, Live View 
display, image review after image capture, image playback, and 
undo last image (p.182). 
Also, only the multiple-exposure image will be saved. (The single 
exposures merged in the multiple-exposure image will not be 
saved.)
P
 Multiple ExposuresN
 
If you set white balance bracketing, the HDR mode or if you shoot a 
movie, multiple exposure shooting cannot be set.
 
If you perform Live View shooting while [On:ContShtng] is set, the Live 
View function will stop automatically after the first shot is taken. From the 
second shot onward, shoot while looking through the viewfinder.