Canon EOS 5D Mark IV L-series Zoom Lens Kit Owner's Manual

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You can shoot two to nine exposures to be merged into one image. With 
Live View shooting (p.297), you can see in real time how the exposures 
are merged when you shoot multiple-exposure images.
1
Press the <b> button.
2
Select Multiple exposure.
 
Select [P], then press <0>.
X
The multiple exposure setting screen 
will appear.
3
Set [Multiple exposure].
 
Select [On:Func/Ctrl] or 
[On:ContShtng], then press <0>.
 
To exit shooting multiple exposures, 
select [Disable].
 
On: Func/Ctrl (Function and control priority)
Useful when you want to shoot multiple exposures while checking 
the result as you proceed. During continuous shooting, the 
continuous shooting speed will decrease greatly.
 
On: ContShtng (Continuous shooting priority)
Geared for continuous multiple-exposure shooting of a moving 
subject. Continuous shooting is possible, but the following 
operations are disabled during shooting: menu viewing, image 
review after image capture, image playback, and undo last image 
(p.274). Also, during Live View shooting, the image displayed will not 
be the final merged image.
Note that only the multiple-exposure image will be saved. (The 
single exposures merged in the multiple-exposure image will not be 
saved.)
P
 Multiple ExposuresN
You can also set multiple exposure with [z3: Multiple exposure].