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Material Safety Data Sheet 
MSDS 2.001.010 
 
2. Hazards 
identification 
A sealed zinc/silver oxide button cell is not hazardous in normal use (as defined in chapter 7). 
In case of mistreatment (prolonged deep discharge, charge, reverse charge, external short circuit…) and in case of 
fault, some electrolyte can leak from the cell. In these cases refer to the risk of potassium hydroxide solution or 
sodium hydroxide solution (corrosive, pH > 14). Charging may cause rupture. The electrode materials are only 
hazardous, if the materials are released by mechanical damaging of the cell or if exposed to fire. 
3. 
Composition/information on ingredients 
Ingredients 
Contents 
CAS No. 
Hazard Symbols 
R Phrases 
Material 
13 – 34 % 
20667-12-3 
O, C, Xi 
R 8-34-44 
Silver oxide 
0 – 14 % 
1313-13-9 
Xn 
R20/22 
Manganese dioxide 
5 – 10 % 
7440-66-6 
R50/53 
Zinc 
0 – 3 % 
1310-58-3 
R22-35 
Potassium hydroxide 
0– 2 % 
1310-73-2 
R35 
Sodium hydroxide 
0,5 – 1,3 % 
< 25 mg/cell 
7439-97-6 
T, N 
R 23-33-50/53 
Mercury (in zinc alloy) 
 
Heavy Metals 
Contents CAS 
No. 
Material 
20 – 60 mg/kg  7439-92-1 
Lead 
< 5 mg/kg 
7440-43-9 
Cadmium 
 
Other Ingredients 
Contents CAS 
No. 
Material 
27 - 70 % 
 
Nickel plated steel 
2 - 5 % 
 
Copper 
2 - 7 % 
 
Polymers 
 
Hazard Symbols 
Xn Harmful 
 T 
Toxic 
 Xi 
Irritating 
 O 
Oxidising 
 C 
Corrosive 
 
Dangerous for the environment 
 
R Phrases 
8 Contact 
with 
combustible 
material may cause fire. 
 
20/22 
Harmful by inhalation and if swallowed. 
 
22 
Harmful if swallowed. 
 
23 
Toxic by inhalation. 
 
33 
Danger of cumulative effects. 
 34 
Causes 
burns. 
 
35 
Causes severe burns. 
 
44 
Risk of explosion if heated under confinement. 
50/53 
Very toxic to aquatic organisms, may cause long-term adverse effects in 
the aquatic environment. 
 
 
Page no.: 
2 of 5 
Edition: 
27.11.08 
Version: 
01 
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VARTA Microbattery GmbH 
Daimlerstraße 1 
73479 Ellwangen 
Germany 
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