Teledyne MODEL T703 Manual Do Utilizador

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Teledyne API T703 Calibrator Operation Manual 
Theory of Operation 
 
165 
9.5. O
3
  GENERATOR OPERATION 
9.5.1. PRINCIPLE OF PHOTOLYTIC O
3
 GENERATION 
Ozone is a naturally occurring substance that is sometimes called "activated oxygen".  It contains three atoms of 
oxygen (O
3
) instead of the usual two found in normal oxygen (O
2
) that is essential for life.  Because of its 
relatively short half-life, ozone cannot be bottled and stored for later use and there fore must always be 
generated on-site by an ozone generator.  The two main principles of ozone generation are UV-light and corona 
discharge.  While the corona-discharge method is most common because of its ability to generate very high 
concentrations (up to 50%), it is inappropriate for calibration needs since the level of fine control over the O
3
 
concentration is poor.  Also, the corona discharge method produces a small amount of NO
2
 as a byproduct, 
which also may be undesirable in a calibration application 
The UV-light method is most feasible in calibration application where production of low, accurate concentrations 
of ozone desired.  This method mimics the radiation method that occurs naturally from the sun in the upper 
atmosphere producing the ozone layer.  An ultra-violet lamp inside the generator emits a precise wavelength of 
UV Light (185 nm).  Ambient air] is passed over an ultraviolet lamp, which splits some of the molecular oxygen 
(O
2
) in the gas into individual oxygen atoms which attach to other existing oxygen molecules (O
2
), forming ozone 
(O
3
).  
 
Figure 9-12: 
O
3
 Generator Internal Pneumatics 
Reference 
Detector
 
U
L
a
m
p
Flow 
Control 
Assembly
To 
Photometer, 
Cal Gas and 
Vent Outlets
 
Inlet from 
Diluent Source 
Valve 
O
2
In
O
3
Out
6O
2
hv
185
= 3O
3
07223B DCN6378