Teledyne T201 Manuel D’Utilisation

Page de 44
T201 Ammonia Analyzer 
Teledyne API Model T201 NH
Analyzer Operator Manual 
10 
07271B DCN6646 
  
1.1  T
HEORY OF 
O
PERATION
 
The Teledyne-API Model T201 analyzer measures ammonia by oxidizing
 
it to nitric oxide by the following reaction: 
4NH
3
 + 5O
2
   
  4NO + 6H
2
The resulting nitric oxide is then measured by the chemiluminescent 
reaction with ozone.  Consult Section 10.1 in the T200 manual (provided 
with this instrument) for more details on the nitric oxide measurement. 
The analyzer uses two converters to oxidize the different sample gases.  A 
high temperature catalytic converter, the M501 NH
3
, converts NH
3
 and 
NOx into NO creating the TN
x
 channel. A second converter, housed inside 
the T201 analyzer and consisting of heated molybdenum, converts all of 
the NO
x
 in the sample to NO producing the NO
x
 channel. The nitric oxide 
channel is measured while bypassing both the M501 NH
3
 and 
molybdenum converter. A Nafion® drier operated in reflux mode, is 
installed prior to the molybdenum converter and the AutoZero valve. The 
drier removes ammonia and water from the switched stream. The 
ammonia would have otherwise been converted by the molybdenum and 
registered as NO
x
. This location provides the drier with continuous flow, 
thereby allowing it to stabilize faster.  
Note 
Due to the Nafion® drier, the analyzer has a maximum ammonia range of 
2.0 PPM. 
The calculated gas concentrations, ammonia and nitrogen dioxide, are 
computed from the differences between the measured channels, as 
outlined in the following equations: 
NO (Nitric Oxide) Concentration = Measured 
TN
x
 (Total Nitrogen) Concentration = Measured (NH
3
 + NO
2
 + NO) 
NO
x
 (Total Nitrogen – Ammonia) Concentration =  
Measured 
(NO
2
 + NO) 
NH
3
 (Ammonia) Concentration = Calculated as follows: 
[(TNx - NOx) / (NH
3
_CE_FACTOR1)] 
NO
2
 (Nitrogen Dioxide) Concentration = Calculated as follows: 
[(NOx – NO) / (NO
2
_CE_FACTOR1)] 
Note 
The
 
nitrogen dioxide efficiency factor (NO
2
_CE_FACTOR1) must be 
calculated by conducting a GPT (gas phase titration) as described in Section 
8.3.3 of the T200 manual and Section 6.0 of 
this manual. This value gives a 
good indication of how well the molybdenum is converting nitrogen dioxide 
into nitric oxide. In a properly functioning analyzer the value should be close 
to 1.0. It is recommended that the molybdenum efficiency be checked every 
three months.